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The color of the emitted light depends on the relative heights of the starting and ending energy levels. A crash between closely spaced levels (such as two and one) releases a pulse of low-energy reddish light, while a crash between more widely spaced levels (say, five and two) releases high-energy purple light.

Sam Kean , in The Disappearing Spoon: And Other True Tales of Madness, Love, and the History of the World from the Periodic Table of the Elements
light energy chemical-reactions electrons electron-shell

Also unlike a planet, an electron—if excited by heat or light—can leap from its low-energy shell to an empty, high-energy shell. The electron cannot stay in the high-energy state for long, so it soon crashes back down. But this isn’t a simple back-and-forth motion, because as it crashes, the electron jettisons energy by emitting light.

Sam Kean , in The Disappearing Spoon: And Other True Tales of Madness, Love, and the History of the World from the Periodic Table of the Elements
energy atoms chemical-reactions electrons electron-shell
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